查尔斯定律计算器

Charles Law

📐 计算公式
查理定律(等压过程):末态体积 V₂ = V₁ × T₂ ÷ T₁(温度须为开尔文 K);联动卡:体积放大倍数 = T₂ ÷ T₁、体积变化量 ΔV = V₂ − V₁。校验:V₁、T₁、T₂ 三项非空合法数值守卫。判据:等压下体积与热力学温度成正比,T₂ > T₁ 膨胀、T₂ < T₁ 收缩。

Charles Law

Formula & Standard References

Item Formula / Note Source / Standard
Charles lawV/T = const at fixed pCharles & Gay-Lussac
Absolute scaleTemperature must be in kelvinKelvin scale
Expansion coefficientα = 1/273.15 K⁻¹ idealThermal expansion
IsobaricConstant pressure and amountIdeal gas law
ValidityValid away from liquefactionEquation of state
ConversionT(K) = t(°C) + 273.15Scale conversion
📌 计算说明
  • V₁/T₁ = V₂/T₂,温度须为开尔文。
  • 0℃→100℃(等压)体积约增 36.6%。

📐 Physical Constants

Constants used on this page and their authoritative sources, for verification and citation

Constant Value Unit Source
Celsius scale zero point T_0 273.15 K SI / ITS-90 defining value (exact)
Boiling point of water (1 atm) 373.15 K ITS-90 (100 ℃ at 1 atm = 101325 Pa)
Standard atmosphere 101 325 Pa ISO 2533 defining value (exact)

Note: Charles's law requires absolute temperature; the isobaric volume ratio from 0 ℃ to 100 ℃ is 373.15/273.15 = 1.3661, i.e. an increase of about 36.61%.

📚 深度解析:查理定律

💡 常见使用场景

0℃→100℃
V1=1 L, T1=273.15 K, T2=373.15 K:V2=V1·T2/T1=1×373.15/273.15=1.366 L。
降温收缩
T2=223 K:V2=0.816 L,体积随绝对温度线性减小。

❓ 常见问题(FAQ)

为何用 K?
比例只对绝对温度成立,摄氏零度仍有体积。
定压条件?
需压强恒定,否则需联合玻意耳定律。