Convert pOH to pH using pH + pOH = 14.00 at 25 °C (and pOH = −log[OH⁻]).
输入氢氧根浓度,求 pOH 与 pH。
| Item | Formula / Note | Source / Standard |
|---|---|---|
| Definition of pOH | pOH = -log10( a_OH- ); concentration approximates activity in dilute solution | IUPAC, Compendium of Chemical Terminology (Gold Book) |
| Relation between pH and pOH | pH + pOH = pK_w, with pK_w ≈ 14.00 at 25 °C | Atkins PW, de Paula J, Physical Chemistry, Oxford Univ. Press |
| Temperature dependence | pK_w varies with temperature, so pH + pOH = 14 holds only near 25 °C | Atkins PW, de Paula J, Physical Chemistry |
| Conversion | At 25 °C, pH = 14.00 - pOH | IUPAC, Compendium of Chemical Terminology (Gold Book) |
Constants used on this page and their authoritative sources, for verification and citation
| Constant | Value | Unit | Source |
|---|---|---|---|
| Ionic product of water K_w (25 ℃) | 1.0e-14 | — | Common convention (this page uses pK_w = 14.00) |
| pK_w of water (CODATA precise value) | 13.997 | — | CODATA 2018 / IUPAC (25 ℃) |
| Neutral pH (25 ℃) | 7.00 | — | Derived from pK_w/2 (IUPAC reference basis) |
| Standard-state concentration c° | 1 | mol·L⁻¹ | IUPAC defining value (exact) |
Note: pH = 14 − pOH holds only at 25 ℃; K_w changes markedly with temperature (pK_w ≈ 14.94 at 0 ℃ and ≈ 12.26 at 100 ℃), so use the pK_w for the actual temperature.
适用于碱性体系 pH 速算:实验室配制 NaOH/氨水等碱液的 pH 核对、废水与清洗液碱度评估、酸碱滴定终点前后 pH 变化预判。
pH 描述水溶液酸碱度:pH<7 酸性、=7 中性、>7 碱性。由 pOH 按 pH=14−pOH(25℃ 标准)换算。
pH+pOH=14 仅在 25℃ 稀溶液中成立;温度变化中性 pH 偏离 7(如 0℃≈7.47、100℃≈6.14)。强酸/强碱高浓度时活度效应明显,需用活度而非浓度。
结果仅供参考,精确测量以 pH 计/试纸为准;腐蚀性液体注意安全。